SME
Organic Chemistry I

Structure and nomenclature

Use this for “Name the alkane CH₃CH(CH₃)CH₂CH(CH₃)CH₃.”

Put in order

Put the steps for naming CH₃CH(CH₃)CH(CH₂CH₃)CH₂CH₂CH₃ in order.
1
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2
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3
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4
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5
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Assumptions

•
The parent is the longest carbon chain; if two chains are equally long, it is the one with more branches.
•
A branch is named from its carbons with -yl: one carbon is methyl, two ethyl, three propyl.
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Two or more of the same branch take di-, tri- or tetra-, with one number for each: 2,4-dimethyl.
•
Numbers are separated by commas, and a number is joined to a word by a hyphen.
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